全文获取类型
收费全文 | 26876篇 |
免费 | 2357篇 |
国内免费 | 3798篇 |
专业分类
化学 | 16534篇 |
晶体学 | 379篇 |
力学 | 2294篇 |
综合类 | 281篇 |
数学 | 9386篇 |
物理学 | 4157篇 |
出版年
2024年 | 27篇 |
2023年 | 235篇 |
2022年 | 331篇 |
2021年 | 551篇 |
2020年 | 816篇 |
2019年 | 779篇 |
2018年 | 713篇 |
2017年 | 947篇 |
2016年 | 1030篇 |
2015年 | 849篇 |
2014年 | 1215篇 |
2013年 | 2201篇 |
2012年 | 1678篇 |
2011年 | 1641篇 |
2010年 | 1498篇 |
2009年 | 1626篇 |
2008年 | 1715篇 |
2007年 | 1787篇 |
2006年 | 1544篇 |
2005年 | 1451篇 |
2004年 | 1339篇 |
2003年 | 1225篇 |
2002年 | 1033篇 |
2001年 | 864篇 |
2000年 | 835篇 |
1999年 | 771篇 |
1998年 | 697篇 |
1997年 | 585篇 |
1996年 | 398篇 |
1995年 | 466篇 |
1994年 | 425篇 |
1993年 | 341篇 |
1992年 | 261篇 |
1991年 | 180篇 |
1990年 | 155篇 |
1989年 | 113篇 |
1988年 | 105篇 |
1987年 | 79篇 |
1986年 | 80篇 |
1985年 | 84篇 |
1984年 | 65篇 |
1983年 | 37篇 |
1982年 | 75篇 |
1981年 | 54篇 |
1980年 | 33篇 |
1979年 | 29篇 |
1978年 | 18篇 |
1977年 | 11篇 |
1976年 | 11篇 |
1972年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 312 毫秒
1.
Patrick Imrie Jianyong Jin 《Journal of polymer science. Part A, Polymer chemistry》2022,60(2):149-174
4D printing is an exciting branch of additive manufacturing. It relies on established 3D printing techniques to fabricate objects in much the same way. However, structures which fall into the 4D printed category have the ability to change with time, hence the “extra dimension.” The common perception of 4D printed objects is that of macroscopic single-material structures limited to point-to-point shape change only, in response to either heat or water. However, in the area of polymer 4D printing, recent advancements challenge this understanding. A host of new polymeric materials have been designed which display a variety of wonderful effects brought about by unconventional stimuli, and advanced additive manufacturing techniques have been developed to accommodate them. As a result, the horizons of polymer 4D printing have been broadened beyond what was initially thought possible. In this review, we showcase the many studies which evolve the very definition of polymer 4D printing, and reveal emerging areas of research integral to its advancement. 相似文献
2.
利用标量化方法建立对称向量拟均衡问题有效解的存在性定理。作为标量化方法的应用,利用这一方法得到向量变分不等式和拟向量变分不等式有效解的存在性定理。 相似文献
3.
Shilin Jiang Dr. Yalan Liu Dr. Lin Wang Prof. Zhifang Chai Prof. Wei-Qun Shi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201145
The coordination chemistry of f-block elements (lanthanide and actinide) in molten salts has become a resounding topic in view of its great importance to the research and development (R&D) of molten salt reactors and pyroprocessing. In this Review article, a general overview of the coordination chemistry of f-block elements in molten salts is provided including past achievements and recent advances. Particular emphases are placed on the oxidation state, speciation, and solution structure of f-block metal ions in molten salts, as well as their relationships with the salt composition. Furthermore, this review briefly discusses the spectroscopic and theoretical methods that complement each other in revealing the coordination properties. 相似文献
4.
5.
6.
Tomoyuki Nakatsuka 《Mathematische Nachrichten》2021,294(1):98-117
We study the existence of a time‐periodic solution with pointwise decay properties to the Navier–Stokes equation in the whole space. We show that if the time‐periodic external force is sufficiently small in an appropriate sense, then there exists a time‐periodic solution of the Navier–Stokes equation such that and uniformly in as . Our solution decays faster than the time‐periodic Stokes fundamental solution and the faster decay of its spatial derivatives of higher order is also described. 相似文献
7.
Jiraya Kiriratnikom Xun Zhang Xiaohan Cao Bo Chu Chengjian Zhang Xinghong Zhang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2262-2268
Facile construction of sulfur-rich polymers using readily available raw chemicals is an area aggressively pursued but challenging. Herein we use common feedstocks of ethylene oxide (EO), propylene oxide (PO), and carbonyl sulfide (COS) to synthesize copoly(thioether)s which are traditionally produced from unpleasant and difficult to store episulfides. In this protocol, the EO/COS coupling selectively generates a pure poly(ethylene sulfide) (PES) with melting temperature (Tm) values up to 172°C and high yields up to 98%. The EO/PO/COS terpolymerization leads to the incorporation of soft poly(propylene sulfide) (PPS) and hard PES segments together, affording a random PES-co-PPS copoly(thioether) with the complete consumption of EO and PO. Additionally, by simply varying the EO/PO feeding ratio, the obtained copoly(thioether)s possess tunable thermal properties, Tm values in the range of 76–144°C, and excellent solubility. These copolymerizations are conducted in one-pot/one-step at industrially favored reaction temperatures of 100–120°C using catalysts of common organic bases, suggesting a facile and practical manner. Especially, the copoly(thioether) exhibits high refractive indices up to 1.68 owing to its high sulfur content, suggesting a broad application prospect in optical materials. 相似文献
8.
《Mendeleev Communications》2022,32(1):105-108
A mixed-metal 1D coordination polymer [CaCu(HBTC)2(H2O)8]n (where H3BTC – benzene-1,3,5-tric arboxylic acid) was obtained in a solvothermal synthesis of a well-known copper-containing metal–organic framework [Cu3(BTC)2(H2O)3]n (HKUST-1) in autoclaves 3D-printed from commercial polypropylene. This material was a source of calcium ions, apparently, leaking from a colorant (calcium carbonate) promoted by glacial acetic acid as a modulator used to produce large single crystals of HKUST-1. This finding was confirmed by elemental analysis and a model experiment that resulted in a new calcium-based 1D coordination polymer [Ca(H2BTC)2(H2O)5]n under the same solvothermal conditions with no copper or calcium salts put into a 3D-printed autoclave. 相似文献
9.
液流电池是一种安全性高、使用寿命长、可扩展的大规模储能系统,可以协助电网调峰储能,提高能源利用率,发展前景广阔。双极板是液流电池的重要组成部分。功能上起到了分隔、串联电池、传导电流、为电堆提供结构支撑等作用。从成本构成角度看,双极板的价格占电堆成本的比重也较大。开发高性能、低成本的双极板对加快液流电池的商业化应用具有重要意义,也是目前业界的迫切需求。虽然文献上报道了许多针对液流电池双极板开发的工作,但是目前高性能、低成本的液流电池双极板产品仍无法充分满足市场需求。本文着重介绍了石墨基复合双极板的研究现状,介绍了材料选择、工艺流程对关键性能的影响,对相关工作进行了评述,并为液流电池双极板的开发提出了建议。 相似文献
10.
《Journal of Pure and Applied Algebra》2022,226(8):107024
We solve a combinatorial question concerning eigenvalues of the universal intertwining endomorphism of a subset representation. 相似文献